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It is suggested that analysis of sedimentary pyrite from the Belingwe sedimentary basin in Zimbabwe may provide evidence for bacterial reduction at this date.
2,500,000,000 to 542,000,000 years ago The Proterozoic Eon: the most recent part of the Precambrian Supereon.
4,540,000,000 (4.54 billion) years ago Formation of planet Earth - Usher's date was ).
Archeozoic: end of Azoic to 2,500,000,000 years ago: The era of the earliest living beings on earth.
"More than 3.5 billion years ago, small single-celled organisms acquired the capacity to photosynthesize" "Plants were restricted to the aquatic world until three billion years later, the first uncontroversial evidence for life is found 2,700,000,000 years ago.
The reference relates to sulphate and iron reduction as early forms of microbial respiration.
It lists (but does not discuss) the intervening millstone grit.
372,200,000 to 358,900 years ago Famennian age of the separated by about 10 million years.